Definitions from Wiktionary (smerk)

▸ adjective:  (obsolete) smart; jaunty; spruce
▸ noun:  Dated form of smirk. [An uneven, often crooked smile that is insolent, self-satisfied, conceited or scornful.]
▸ verb:  Dated form of smirk. [To smile in a way that is affected, smug, insolent or contemptuous.]

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